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    This flotation step is conducted at alkaline pH. In the case where galena is floated and the copper minerals are depressed, copper depression can be achieved by using sodium sulphide, hydrosulfite, lime, cyanide, zinc-cyanide and/or ferricyanide complexes. Selection of flotation reagents and frothers is an important, even critical, consideration.

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    The relative galena and sphalerite contents do not change the surface chemistry and tend only to have an impact in cases where the galena content is higher than the sphalerite content, e.g. at Cannington where if the lead feed grade relative to zinc is too high, then too much of the faster floating zinc with lower iron content is recovered to the lead

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    The copper ions replace zinc atoms on the sphalerite surface creating a pseudocopper mineral surface coverage on the sphalerite which is then collected using copper flotation type collectors. Because most of the iron sulphides also report to the lead flotation tails and so feeds the zinc flotation circuit, typically lime is used to raise pH for iron sulphide

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    This flotation step is conducted at alkaline pH. In the case where galena is floated and the copper minerals are depressed, copper depression can be achieved by using sodium sulphide, hydrosulfite, lime, cyanide, zinc-cyanide and/or ferricyanide complexes. Selection of flotation reagents and frothers is an important, even critical, consideration.

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